Hydroxide

Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. A hydroxide attached to a strongly electropositive center may itself ionize, liberating a hydrogen cation (H+), making the parent compound an acid. Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. A hydroxide attached to a strongly electropositive center may itself ionize, liberating a hydrogen cation (H+), making the parent compound an acid. The corresponding electrically neutral compound HO• is the hydroxyl radical. The corresponding covalently-bound group –OH of atoms is the hydroxy group.Hydroxide ion and hydroxy group are nucleophiles and can act as a catalysts in organic chemistry. Many inorganic substances which bear the word 'hydroxide' in their names are not ionic compounds of the hydroxide ion, but covalent compounds which contain hydroxy groups. The hydroxide ion is a natural part of water, because of the self-ionization reaction in which its complement, hydronium, is passed hydrogen: The equilibrium constant for this reaction, defined as has a value close to 10−14 at 25 °C, so the concentration of hydroxide ions in pure water is close to 10−7 mol∙dm−3, in order to satisfy the equal charge constraint. The pH of a solution is equal to the decimal cologarithm of the hydrogen cation concentration; the pH of pure water is close to 7 at ambient temperatures. The concentration of hydroxide ions can be expressed in terms of pOH, which is close to (14 − pH), so the pOH of pure water is also close to 7. Addition of a base to water will reduce the hydrogen cation concentration and therefore increase the hydroxide ion concentration (increase pH, decrease pOH) even if the base does not itself contain hydroxide. For example, ammonia solutions have a pH greater than 7 due to the reaction NH3 + H+ ⇌ NH+4, which decreases the hydrogen cation concentration, which increases the hydroxide ion concentration. pOH can be kept at a nearly constant value with various buffer solutions. In aqueous solution the hydroxide ion is a base in the Brønsted–Lowry sense as it can accept a proton from a Brønsted–Lowry acid to form a water molecule. It can also act as a Lewis base by donating a pair of electrons to a Lewis acid. In aqueous solution both hydrogen and hydroxide ions are strongly solvated, with hydrogen bonds between oxygen and hydrogen atoms. Indeed, the bihydroxide ion H3O−2 has been characterized in the solid state. This compound is centrosymmetric and has a very short hydrogen bond (114.5 pm) that is similar to the length in the bifluoride ion HF−2 (114 pm). In aqueous solution the hydroxide ion forms strong hydrogen bonds with water molecules. A consequence of this is that concentrated solutions of sodium hydroxide have high viscosity due to the formation of an extended network of hydrogen bonds as in hydrogen fluoride solutions. In solution, exposed to air, the hydroxide ion reacts rapidly with atmospheric carbon dioxide, acting as an acid, to form, initially, the bicarbonate ion. The equilibrium constant for this reaction can be specified either as a reaction with dissolved carbon dioxide or as a reaction with carbon dioxide gas (see Carbonic acid for values and details). At neutral or acid pH, the reaction is slow, but is catalyzed by the enzyme carbonic anhydrase, which effectively creates hydroxide ions at the active site.