Refining (metallurgy)

In metallurgy, refining consists of purifying an impure metal. It is to be distinguished from other processes such as smelting and calcining in that those two involve a chemical change to the raw material, whereas in refining, the final material is usually identical chemically to the original one, only it is purer. The processes used are of many types, including pyrometallurgical and hydrometallurgical techniques. In metallurgy, refining consists of purifying an impure metal. It is to be distinguished from other processes such as smelting and calcining in that those two involve a chemical change to the raw material, whereas in refining, the final material is usually identical chemically to the original one, only it is purer. The processes used are of many types, including pyrometallurgical and hydrometallurgical techniques. One ancient process for extracting the silver from lead was cupellation. Lead was melted in a bone ash 'test' or 'cupel' and air blown across the surface. This oxidised the lead to litharge, troy ounces of silver per ton of lead (178 ppm). In the 18th century, the process was carried on using a kind of reverberatory furnace, but differing from the usual kind in that air was blown over the surface of the molten lead from bellows or (in the 19th century) blowing cylinders. The Pattinson process was patented by its inventor, Hugh Lee Pattinson, in 1833. It depended on well-known material properties; essentially that lead and silver melt at different temperatures. The equipment consisted of a row of about 8–9 iron pots, which could be heated from below. Argentiferous lead was charged to the central pot and melted. This was then allowed to cool, as the lead solidified, it was skimmed off and moved to the next pot in one direction, and the remaining metal was then transferred to the next pot in the opposite direction. The process was repeated in the pots successively, and resulted in lead accumulating in the pot at one end and silver in that at the other. The process was economic for lead containing at least 250 grams of silver per ton. The Parkes process, patented in 1850 uses zinc to form a material which the silver enters. This floats on the lead and can be skimmed off. The silver is then recovered by volatalising the zinc. The initial product of copper smelting was impure black copper, which was then repeatedly melted to purify it, alternately oxidizing and reducing it. In one of the melting stages, lead was added. Gold and silver preferentially dissolved in this, thus providing a means of recovering these precious metals. To produce purer copper suitable for making copper plates or hollow-ware, further melting processes were undertaken, using charcoal as fuel. The repeated application of such fire-refining processes was capable of producing copper that was 99.25% pure. The purest copper is obtained by an electrolytic process, undertaken using a slab of impure copper as the anode and a thin sheet of pure copper as the cathode. The electrolyte is an acidic solution of copper sulphate. By passing electricity through the cell, copper is dissolved from the anode and deposited on the cathode. However impurities either remain in solution or collect as an insoluble sludge. This process only became possible following the invention of the dynamo; it was first used in South Wales in 1869. The product of the blast furnace is pig iron, which contains 4–5% carbon and usually some silicon. To produce a forgeable product a further process was needed, usually described as fining, rather than refining. From the 16th century, this was undertaken in a finery forge. At the end of the 18th century, this began to be replaced by puddling (in a puddling furnace), which was in turn gradually superseded by the production of mild steel by the Bessemer process. The term refining is used in a narrower context. Henry Cort's original puddling process only worked where the raw material was white cast iron, rather than the grey pig iron that was the usual raw material for finery forges. To use grey pig iron, a preliminary refining process was necessary to remove silicon. The pig iron was melted in a running out furnace and then run out into a trough. This process oxidised the silicon to form a slag, which floated on the iron and was removed by lowering a dam at the end of the trough. The product of this process was a white metal, known as finers metal or refined iron.