Yttrium(III) chloride

Yttrium(III) chloride is an inorganic compound of yttrium and chloride. It exists in two forms, the hydrate (YCl3(H2O)6) and an anhydrous form (YCl3). Both are colourless solids that are highly soluble in water and deliquescent. Solid YCl3 adopts a cubic structure with close-packed chloride ions and yttrium ions filling one third of the octahedral holes and the resulting YCl6 octahedra sharing three edges with adjacent octahedra, giving it a layered structure. This structure is shared by a range of compounds, notably AlCl3.YCl3 is often prepared by the 'ammonium chloride route,' starting from either Y2O3 or hydrated chloride or oxychloride. or YCl3·6H2O. These methods produce (NH4)2: