Red mud

Bauxite tailings, also known as red mud, red sludge, bauxite residue, or alumina refinery residues (ARR), is a highly alkaline waste product composed mainly of iron oxide that is generated in the industrial production of alumina (aluminium oxide, the principal raw material used in the manufacture of aluminium metal and also widely used in the manufacture of ceramics, abrasives and refractories). Annually, about 77 million tons of the red special waste are produced, causing a serious disposal problem in the mining industry. The scale of production makes the waste product an important one, and issues with its storage are reviewed and every opportunity is explored to find uses for it. Bauxite tailings, also known as red mud, red sludge, bauxite residue, or alumina refinery residues (ARR), is a highly alkaline waste product composed mainly of iron oxide that is generated in the industrial production of alumina (aluminium oxide, the principal raw material used in the manufacture of aluminium metal and also widely used in the manufacture of ceramics, abrasives and refractories). Annually, about 77 million tons of the red special waste are produced, causing a serious disposal problem in the mining industry. The scale of production makes the waste product an important one, and issues with its storage are reviewed and every opportunity is explored to find uses for it. Over 95% of the alumina produced globally is through the Bayer process; for every tonne of alumina produced, approximately 1 to 1.5 tonnes of bauxite tailings/residue are also produced. Annual production of alumina in 2018 was approximately 126 million tonnes resulting in the generation of over 160 million tonnes of bauxite tailings/residue. Red mud is a side-product of the Bayer process, the principal means of refining bauxite en route to alumina. The resulting alumina is the raw material for producing aluminium by the Hall–Héroult process. A typical bauxite plant produces one to two times as much red mud as alumina. This ratio is dependent on the type of bauxite used in the refining process and the extraction conditions. There are over 60 manufacturing operations across the world using the Bayer process to make alumina from bauxite ore. Bauxite ore is mined, normally in open cast mines, and transferred to an alumina refinery for processing. The alumina is extracted using sodium hydroxide under conditions of high temperature and pressure. The insoluble part of the bauxite (the residue) is removed, giving rise to a solution of sodium aluminate, which is then seeded with an aluminium hydroxide crystal and allowed to cool which causes the remaining aluminium hydroxide to precipitate from the solution. Some of the aluminium hydroxide is used to seed the next batch, while the remainder is calcined (heated) at over 1000 °C in rotary kilns or fluid flash calciners to produce aluminium oxide (alumina). The alumina content of the bauxite used is normally between 45 - 50%, but ores with a wide range of alumina contents can be used. The aluminium compound may be present as gibbsite (Al(OH)3), boehmite (γ-AlO(OH)) or diaspore (α-AlO(OH)). The tailings/residue invariably has a high concentration of iron oxide which gives the product a characteristic red colour. A small residual amount of the sodium hydroxide used in the process remains with the tailings, causing the material to have a high pH/alkalinity, normally >12. Various stages in the solid/liquid separation process are introduced to recycle as much sodium hydroxide as possible from the residue back into the Bayer Process in order to make the process as efficient as possible and reduce production costs. This also lowers the final alkalinity of the tailings making it easier and safer to handle and store. Red mud is composed of a mixture of solid and metallic oxides. The red colour arises from iron oxides, which comprise up to 60% of the mass. The mud is highly basic with a pH ranging from 10 to 13. In addition to iron, the other dominant components include silica, unleached residual alumina, and titanium oxide.