Atmosphere of Earth

The atmosphere of Earth is the layer of gases, commonly known as air, that surrounds the planet Earth and is retained by Earth's gravity. The atmosphere of Earth protects life on Earth by creating pressure allowing for liquid water to exist on the Earth's surface, absorbing ultraviolet solar radiation, warming the surface through heat retention (greenhouse effect), and reducing temperature extremes between day and night (the diurnal temperature variation). By volume, dry air contains 78.09% nitrogen, 20.95% oxygen, 0.93% argon, 0.04% carbon dioxide, and small amounts of other gases. Air also contains a variable amount of water vapor, on average around 1% at sea level, and 0.4% over the entire atmosphere. Air composition, temperature, and atmospheric pressure vary with altitude, and air suitable for use in photosynthesis by terrestrial plants and breathing of terrestrial animals is found only in Earth's troposphere and in artificial atmospheres. The atmosphere has a mass of about 5.15×1018 kg, three quarters of which is within about 11 km (6.8 mi; 36,000 ft) of the surface. The atmosphere becomes thinner and thinner with increasing altitude, with no definite boundary between the atmosphere and outer space. The Kármán line, at 100 km (62 mi), or 1.57% of Earth's radius, is often used as the border between the atmosphere and outer space. Atmospheric effects become noticeable during atmospheric reentry of spacecraft at an altitude of around 120 km (75 mi). Several layers can be distinguished in the atmosphere, based on characteristics such as temperature and composition. The study of Earth's atmosphere and its processes is called atmospheric science (aerology). Early pioneers in the field include Léon Teisserenc de Bort and Richard Assmann. The three major constituents of Earth's atmosphere are nitrogen, oxygen, and argon. Water vapor accounts for roughly 0.25% of the atmosphere by mass. The concentration of water vapor (a greenhouse gas) varies significantly from around 10 ppm by volume in the coldest portions of the atmosphere to as much as 5% by volume in hot, humid air masses, and concentrations of other atmospheric gases are typically quoted in terms of dry air (without water vapor). The remaining gases are often referred to as trace gases, among which are the greenhouse gases, principally carbon dioxide, methane, nitrous oxide, and ozone. Besides argon, already mentioned, other noble gases, neon, helium, krypton, and xenon are also present. Filtered air includes trace amounts of many other chemical compounds. Many substances of natural origin may be present in locally and seasonally variable small amounts as aerosols in an unfiltered air sample, including dust of mineral and organic composition, pollen and spores, sea spray, and volcanic ash. Various industrial pollutants also may be present as gases or aerosols, such as chlorine (elemental or in compounds), fluorine compounds and elemental mercury vapor. Sulfur compounds such as hydrogen sulfide and sulfur dioxide (SO2) may be derived from natural sources or from industrial air pollution. The relative concentration of gases remains constant until about 10,000 m (33,000 ft). In general, air pressure and density decrease with altitude in the atmosphere. However, temperature has a more complicated profile with altitude, and may remain relatively constant or even increase with altitude in some regions (see the temperature section, below). Because the general pattern of the temperature/altitude profile, or lapse rate, is constant and measurable by means of instrumented balloon soundings, the temperature behavior provides a useful metric to distinguish atmospheric layers. In this way, Earth's atmosphere can be divided (called atmospheric stratification) into five main layers. Excluding the exosphere, the atmosphere has four primary layers, which are the troposphere, stratosphere, mesosphere, and thermosphere. From highest to lowest, the five main layers are: The exosphere is the outermost layer of Earth's atmosphere (i.e. the upper limit of the atmosphere). It extends from the exobase, which is located at the top of the thermosphere at an altitude of about 700 km above sea level, to about 10,000 km (6,200 mi; 33,000,000 ft) where it merges into the solar wind.