Lanthanide

The lanthanide (/ˈlænθənaɪd/) or lanthanoid (/ˈlænθənɔɪd/) series of chemical elements comprises the 15 metallic chemical elements with atomic numbers 57 through 71, from lanthanum through lutetium. These elements, along with the chemically similar elements scandium and yttrium, are often collectively known as the rare earth elements.Primordial  From decay  Synthetic Border shows natural occurrence of the element4f14 The lanthanide (/ˈlænθənaɪd/) or lanthanoid (/ˈlænθənɔɪd/) series of chemical elements comprises the 15 metallic chemical elements with atomic numbers 57 through 71, from lanthanum through lutetium. These elements, along with the chemically similar elements scandium and yttrium, are often collectively known as the rare earth elements. The informal chemical symbol Ln is used in general discussions of lanthanide chemistry to refer to any lanthanide. All but one of the lanthanides are f-block elements, corresponding to the filling of the 4f electron shell; depending on the source, either lanthanum or lutetium is considered a d-block element, but is included due to its chemical similarities with the other 14. All lanthanide elements form trivalent cations, Ln3+, whose chemistry is largely determined by the ionic radius, which decreases steadily from lanthanum to lutetium. They are called lanthanides because the elements in the series are chemically similar to lanthanum. Both lanthanum and lutetium have been labeled as group 3 elements, because they have a single valence electron in the 5d shell. However, both elements are often included in discussions of the chemistry of lanthanide elements. Lanthanum is the more often omitted of the two, because its placement as a group 3 element is somewhat more common in texts and for semantic reasons: since 'lanthanide' means 'like lanthanum', it has been argued that lanthanum cannot logically be a lanthanide, but IUPAC acknowledges its inclusion based on common usage. In presentations of the periodic table, the lanthanides and the actinides are customarily shown as two additional rows below the main body of the table, with placeholders or else a selected single element of each series (either lanthanum and actinium, or lutetium and lawrencium) shown in a single cell of the main table, between barium and hafnium, and radium and rutherfordium, respectively. This convention is entirely a matter of aesthetics and formatting practicality; a rarely used wide-formatted periodic table inserts the lanthanide and actinide series in their proper places, as parts of the table's sixth and seventh rows (periods). The 1985 International Union of Pure and Applied Chemistry “Red Book” (p. 45) recommends that 'lanthanoid' is used rather than 'lanthanide'. The ending “-ide” normally indicates a negative ion. However, owing to wide current use, “lanthanide” is still allowed. Together with the two elements at the top of group 3, scandium and yttrium, the trivial name 'rare earths' is sometimes used to describe all the lanthanides; a definition of rare earths including the group 3, lanthanide, and actinide elements is also occasionally seen, and rarely Sc + Y + lanthanides + thorium. The 'earth' in the name 'rare earths' arises from the minerals from which they were isolated, which were uncommon oxide-type minerals. However, the use of the name is deprecated by IUPAC, as the elements are neither rare in abundance nor 'earths' (an obsolete term for water-insoluble strongly basic oxides of electropositive metals incapable of being smelted into metal using late 18th century technology). Group 2 is known as the alkaline earth elements for much the same reason. The 'rare' in the 'rare earths' name has much more to do with the difficulty of separating out each of the individual lanthanide elements than scarcity of any of them. By way of the Greek 'dysprositos' for 'hard to get at,' element 66, dysprosium was similarly named; lanthanum itself is named after a word for 'hidden.' The elements 57 (La) to 71 (Lu) are very similar chemically to one another and frequently occur together in nature, often anywhere from three to all 15 of the lanthanides (along with yttrium as a 16th) occur in minerals such as samarskite, monazite and many others which can also contain the other two group 3 elements as well as thorium and occasionally other actinides as well. A majority of the rare earths were discovered at the same mine in Ytterby, Sweden and four of them are named (yttrium, ytterbium, erbium, terbium) after the city and a fifth *(holmium) after Stockholm; scandium is named after Scandinavia, thulium after the old name Thule, and the immediately-following group 4 element (number 72) hafnium is named for the Latin name of the city of Copenhagen. Samarskite (a mineral which is the source of the name of the element samarium) and other similar minerals in particular also have these elements in association with the nearby metals tantalum, niobium, hafnium, zirconium, vanadium, and titanium, from group 4 and group 5 often in similar oxidation states. Monazite is a phosphate of numerous group 3 + lanthanide + actinide metals and mined especially for the thorium content and specific rare earths especially lanthanum, yttrium and cerium. Cerium and lanthanum as well as other members of the rare earth series are often produced as a metal called mischmetal containing a variable mixture of these elements with cerium and lanthanum predominating; it has direct uses such as lighter flints and other spark sources which do not require extensive purification of one of these metals. There are also rare earth-bearing minerals based on group 2 elements such as yttrocalcite, yttrocerite, yttrofluorite which vary in content of yttrium, cerium, and lanthanum in a particular as well as varying amounts of the others. Other lanthanide/rare earth minerals include bastnäsite, florencite, chernovite, perovskite, xenotime, cerite, gadolinite, lanthanite, fergusonite, polycrase, blomstrandine, håleniusite, miserite, loparite, lepersonnite, euxenite, all of which have a range of relative element concentration and may have the symbol of a predominating one such as monazite-ce; group 3 elements do not occur as native element minerals in the fashion of gold, silver, tantalum and many others on earth but may in lunar regolith. Very rare cerium, lanthanum, and presumably other lanthanide/group 3 halides, feldspars and garnets are also known to exist. All of this is the result of the order in which the electron shells of these elements are filled—the outermost has the same configuration for all of them, and a deeper shell is progressively filled with electrons as the atomic number increases from 57 towards 71. For many years, mixtures of more than one rare earth were considered to be single elements, such as neodymium and praseodymium being thought to be the single element didymium and so on. Very small differences in solubility are used in solvent and ion-exchange purification methods for these elements which require a great deal of repeating to get a purified metal. The refined metals and their compounds have subtle and stark differences amongst themselves in electronic, electrical, optical, and magnetic properties which account for their many niche uses.