Uranium-thorium dating

Uranium–thorium dating, also called thorium-230 dating, uranium-series disequilibrium dating or uranium-series dating, is a radiometric dating technique established in the 1960s which has been used since the 1970s to determine the age of calcium carbonate materials such as speleothem or coral. Unlike other commonly used radiometric dating techniques such as rubidium–strontium or uranium–lead dating, the uranium-thorium technique does not measure accumulation of a stable end-member decay product. Instead, it calculates an age from the degree to which secular equilibrium has been restored between the radioactive isotope thorium-230 and its radioactive parent uranium-234 within a sample. Uranium–thorium dating, also called thorium-230 dating, uranium-series disequilibrium dating or uranium-series dating, is a radiometric dating technique established in the 1960s which has been used since the 1970s to determine the age of calcium carbonate materials such as speleothem or coral. Unlike other commonly used radiometric dating techniques such as rubidium–strontium or uranium–lead dating, the uranium-thorium technique does not measure accumulation of a stable end-member decay product. Instead, it calculates an age from the degree to which secular equilibrium has been restored between the radioactive isotope thorium-230 and its radioactive parent uranium-234 within a sample. Thorium is not soluble in natural water under conditions found at or near the surface of the earth, so materials grown in or from this water do not usually contain thorium. In contrast, uranium is soluble to some extent in all natural water, so any material that precipitates or is grown from such water also contains trace uranium, typically at levels of between a few parts per billion and few parts per million by weight. As time passes after such material has formed, uranium-234 in the sample with a half-life of 245,000 years decays to thorium-230. Thorium-230 is itself radioactive with a half-life of 75,000 years, so instead of accumulating indefinitely (as for instance is the case for the uranium–lead system), thorium-230 instead approaches secular equilibrium with its radioactive parent uranium-234. At secular equilibrium, the number of thorium-230 decays per year within a sample is equal to the number of thorium-230 produced, which also equals the number of uranium-234 decays per year in the same sample. In 1908, John Joly, a professor of geology from the University of Dublin, found higher radium contents in deep sediments than in those of the continental shelf, and suspected that detrital sediments scavenged radium out of seawater.Piggot and Urry found in 1942, that radium excess corresponded with an excess of thorium. It took another 20 years until the technique was applied to terrestrial carbonates (speleothems and travertines). In the late 80's the method was refined by mass spectrometry. After Viktor Viktorovich Cherdyntsev's landmark book about uranium-234 had been translated into English, U-Th dating came to widespread research attention in Western geology.:7(subscription required)