Helium compounds

Helium is the most unreactive element, so it was commonly believed that helium compounds do not exist at all. Helium's first ionization energy of 24.57 eV is the highest of any element. Helium has a complete shell of electrons, and in this form the atom does not readily accept any extra electrons or join with anything to make covalent compounds. The electron affinity is 0.080 eV, which is very close to zero. The helium atom is small with the radius of the outer electron shell at 0.29 Å. The atom is very hard with a Pearson's hardness of 12.3 eV. It has the lowest polarizability of any kind of atom. However very weak van der Waals forces exist between helium and other atoms. This force may exceed repulsive forces. So at extremely low temperatures helium may form van der Waals molecules. Helium is the most unreactive element, so it was commonly believed that helium compounds do not exist at all. Helium's first ionization energy of 24.57 eV is the highest of any element. Helium has a complete shell of electrons, and in this form the atom does not readily accept any extra electrons or join with anything to make covalent compounds. The electron affinity is 0.080 eV, which is very close to zero. The helium atom is small with the radius of the outer electron shell at 0.29 Å. The atom is very hard with a Pearson's hardness of 12.3 eV. It has the lowest polarizability of any kind of atom. However very weak van der Waals forces exist between helium and other atoms. This force may exceed repulsive forces. So at extremely low temperatures helium may form van der Waals molecules. Repulsive forces between helium and other atoms may be overcome by high pressures. Helium has been shown to form a crystalline compound with sodium under pressure. Suitable pressures to force helium into solid combinations could be found inside planets. Clathrates are also possible with helium under pressure in ice, and other small molecules such as nitrogen. Other ways to make helium reactive are: to convert it into an ion, or to excite an electron to a higher level, allowing it to form excimers. Ionised helium (He+), also known as He II, is a very high energy material able to extract an electron from any other atom. He+ has an electron configuration like hydrogen, so as well as being ionic it can form covalent bonds. Excimers do not last for long, as the molecule containing the higher energy level helium atom can rapidly decay back to a repulsive ground state, where the two atoms making up the bond repel. However, in some locations such as helium white dwarfs, conditions may be suitable to rapidly form excited helium atoms. The excited helium atom has a 1s electron promoted to 2s. This requires 1,900 kilojoules (450 kcal) per gram of helium, which can be supplied by electron impact, or electric discharge. The 2s excited electron state resembles that of the lithium atom.