Dispersion (chemistry)

A dispersion is a system in which distributed particles of one material are dispersed in a continuous phase of another material. The two phases may be in the same or different states of matter. A dispersion is a system in which distributed particles of one material are dispersed in a continuous phase of another material. The two phases may be in the same or different states of matter. Dispersions are classified in a number of different ways, including how large the particles are in relation to the particles of the continuous phase, whether or not precipitation occurs, and the presence of Brownian motion. In general, dispersions of particles sufficiently large for sedimentation are called suspensions, while those of smaller particles are called colloids and solutions. Dispersions do not display any structure; i.e., the particles (or in case of emulsions: droplets) dispersed in the liquid or solid matrix (the 'dispersion medium') are assumed to be statistically distributed. Therefore, for dispersions, usually percolation theory is assumed to appropriately describe their properties. However, percolation theory can be applied only if the system it should describe is in or close to thermodynamic equilibrium. There are only very few studies about the structure of dispersions (emulsions), although they are plentiful in type and in use all over the world in innumerable applications (see below). In the following, only such dispersions with a dispersed phase diameter of less than 1 µm will be discussed. To understand the formation and properties of such dispersions (incl emulsions), it must be considered that the dispersed phase exhibits a 'surface', which is covered ('wet') by a different 'surface' that, hence, are forming an interface (chemistry). Both surfaces have to be created (which requires a huge amount of energy), and the interfacial tension (difference of surface tension) is not compensating the energy input, if at all. Experimental evidence suggests dispersions have a structure very much different from any kind of statistical distribution (which would be characteristics for a system in thermodynamic equilibrium), but in contrast display structures similar to self-organisation, which can be described by non-equilibrium thermodynamics. This is the reason why some liquid dispersions turn to become gels or even solid at a concentration of a dispersed phase above a critical concentration (which is dependent on particle size and interfacial tension). Also, the sudden appearance of conductivity in a system of a dispersed conductive phase in an insulating matrix has been explained. Dispersion is a process by which (in the case of solid dispersing in a liquid) agglomerated particles are separated from each other and a new interface between the inner surface of the liquid dispersion medium and the surface of the dispersed particles is generated. This process is facilitated by molecular diffusion and convection.