Sodium superoxide is the inorganic compound with the formula NaO2. This yellow-orange solid is a salt of the superoxide anion. It is an intermediate in the oxidation of sodium by oxygen. Sodium superoxide is the inorganic compound with the formula NaO2. This yellow-orange solid is a salt of the superoxide anion. It is an intermediate in the oxidation of sodium by oxygen. NaO2 is prepared by treating sodium peroxide with oxygen at high pressures: