Permeation

In physics and engineering, permeation (also called imbuing) is the penetration of a permeate (such as a liquid, gas, or vapor) through a solid. It is directly related to the concentration gradient of the permeate, a material's intrinsic permeability, and the materials' mass diffusivity. Permeation is modeled by equations such as Fick's laws of diffusion, and can be measured using tools such as a minipermeameter. In physics and engineering, permeation (also called imbuing) is the penetration of a permeate (such as a liquid, gas, or vapor) through a solid. It is directly related to the concentration gradient of the permeate, a material's intrinsic permeability, and the materials' mass diffusivity. Permeation is modeled by equations such as Fick's laws of diffusion, and can be measured using tools such as a minipermeameter. The process of permeation involves the diffusion of molecules, called the permeant, through a membrane or interface. Permeation works through diffusion; the permeant will move from high concentration to low concentration across the interface. A material can be semipermeable, with the presence of a semipermeable membrane. Only molecules or ions with certain properties will be able to diffuse across such a membrane. This is a very important mechanism in biology where fluids inside a blood vessel need to be regulated and controlled. Permeation can occur through most materials including metals, ceramics and polymers. However, the permeability of metals is much lower than that of ceramics and polymers due to their crystal structure and porosity. Permeation is something that must be considered carefully in many polymer applications, due to their high permeability. Permeability depends on the temperature of the interaction as well as the characteristics of both the polymer and the permeant component. Through the process of sorption, molecules of the permeant can be either absorbed or desorbed at the interface. The permeation of a material can be measured through numerous methods that quantify the permeability of a substance through a specific material. Permeability due to diffusion is measured in SI units of mol/(m･s･Pa) although Barrers are also commonly used. Permeability due to diffusion is not to be confused with Permeability (earth sciences) due to fluid flow in porous solids measured in Darcy. Nollet tried to seal wine containers with a pig's bladder and stored them under water. After a while the bladder bulged outwards. He noticed the high pressure that discharged after he pierced the bladder. Curious, he did the experiment the other way round: he filled the container with water and stored it in wine. The result was a bulging inwards of the bladder. His notes about this experiment are the first scientific mention of permeation (later it would be called semipermeability). Graham experimentally proved the dependency of gas diffusion on molecular weight, which is now known as Graham's law. Barrer developed the modern Barrer measurement technique, and first used scientific methods for measuring permeation rates. The permeation of films and membranes can be measured with any gas or liquid. One method uses a central module which is separated by the test film: the testing gas is fed on the one side of the cell and the permeated gas is carried to the detector by a sweep gas. The diagram on the right shows a testing cell for films, normally made from metals like stainless steel. The photo shows a testing cell for pipes made from glass, similar to a Liebig condenser. The testing medium (liquid or gas) is situated in the inner white pipe and the permeate is collected in the space between the pipe and the glass wall. It is transported by a sweep gas (connected to the upper and lower joint) to an analysing device.