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Peterson olefination

The Peterson olefination (also called the Peterson reaction) is the chemical reaction of α-silyl carbanions (1 in diagram below) with ketones (or aldehydes) to form a β-hydroxysilane (2) which eliminates to form alkenes (3). Several reviews have been published.

[ "Photochemistry", "Medicinal chemistry", "Organic chemistry", "Inorganic chemistry", "Stereochemistry" ]
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