Bentonite

Bentonite (/ˈbɛntənʌɪt/) is an absorbent aluminium phyllosilicate clay consisting mostly of montmorillonite. It was named by Wilbur C. Knight in 1898 after the Cretaceous Benton Shale near Rock River, Wyoming. Bentonite (/ˈbɛntənʌɪt/) is an absorbent aluminium phyllosilicate clay consisting mostly of montmorillonite. It was named by Wilbur C. Knight in 1898 after the Cretaceous Benton Shale near Rock River, Wyoming. The different types of bentonite are each named after the respective dominant element, such as potassium (K), sodium (Na), calcium (Ca), and aluminium (Al). Experts debate a number of nomenclatorial problems with the classification of bentonite clays. Bentonite usually forms from weathering of volcanic ash, most often in the presence of water. However, the term bentonite, as well as a similar clay called tonstein, has been used to describe clay beds of uncertain origin. For industrial purposes, two main classes of bentonite exist: sodium and calcium bentonite. In stratigraphy and tephrochronology, completely devitrified (weathered volcanic glass) ash-fall beds are commonly referred to as K-bentonites when the dominant clay species is illite. In addition to montmorillonite and illite another common clay species that is sometimes dominant is kaolinite. Kaolinite-dominated clays are commonly referred to as tonsteins and are typically associated with coal. Sodium bentonite expands when wet, absorbing as much as several times its dry mass in water. Because of its excellent colloidal properties, it is often used in drilling mud for oil and gas wells and boreholes for geotechnical and environmental investigations. The property of swelling also makes sodium bentonite useful as a sealant, since it provides a self-sealing, low permeability barrier. It is used to line the base of landfills, for example. Various surface modifications to sodium bentonite improve some rheological or sealing performance in geoenvironmental applications, for example, the addition of polymers. Calcium bentonite is a useful adsorbent of ions in solution, as well as fats and oils. It is the main active ingredient of fuller's earth, probably one of the earliest industrial cleaning agents. Calcium bentonite may be converted to sodium bentonite (termed sodium beneficiation or sodium activation) to exhibit many of sodium bentonite's properties by an ion exchange process. In common usage, this means adding 5–10% of a soluble sodium salt such as sodium carbonate to wet bentonite, mixing well, and allowing time for the ion exchange to take place and water to remove the exchanged calcium. Some properties, such as viscosity and fluid loss of suspensions, of sodium-beneficiated calcium bentonite (or sodium-activated bentonite) may not be fully equivalent to those of natural sodium bentonite. For example, residual calcium carbonates (formed if exchanged cations are insufficiently removed) may result in inferior performance of the bentonite in geosynthetic liners. Also known as potash bentonite or K-bentonite, potassium bentonite is a potassium-rich illitic clay formed from alteration of volcanic ash. The main uses of bentonite are for drilling mud, binder (e.g. foundry-sand bond, iron ore pelletizer), purifier, absorbent (e.g. pet litter), and as a groundwater barrier. As of around 1990, almost half of the US production of bentonite was used for drilling mud. Bentonite is used in drilling fluids to lubricate and cool the cutting tools, to remove cuttings, and to help prevent blowouts. Much of bentonite's usefulness in the drilling and geotechnical engineering industry comes from its unique rheological properties. Relatively small quantities of bentonite suspended in water form a viscous, shear-thinning material. Most often, bentonite suspensions are also thixotropic, although rare cases of rheopectic behavior have also been reported. At high enough concentrations (about 60 grams of bentonite per litre of suspension), bentonite suspensions begin to take on the characteristics of a gel (a fluid with a minimum yield strength required to make it move). So, it is a common component of drilling mud used to curtail drilling fluid invasion by its propensity for aiding in the formation of mud cake. Bentonite has been widely used as a foundry-sand bond in iron and steel foundries. Sodium bentonite is most commonly used for large castings that use dry molds, while calcium bentonite is more commonly used for smaller castings that use 'green' or wet molds. Bentonite is also used as a binding agent in the manufacture of iron ore (taconite) pellets as used in the steelmaking industry.Bentonite, in small percentages, is used as an ingredient in commercially designed clay bodies and ceramic glazes.