Solution of Schrödinger equation for a step potential

In quantum mechanics and scattering theory, the one-dimensional step potential is an idealized system used to model incident, reflected and transmitted matter waves. The problem consists of solving the time-independent Schrödinger equation for a particle with a step-like potential in one dimension. Typically, the potential is modelled as a Heaviside step function. In quantum mechanics and scattering theory, the one-dimensional step potential is an idealized system used to model incident, reflected and transmitted matter waves. The problem consists of solving the time-independent Schrödinger equation for a particle with a step-like potential in one dimension. Typically, the potential is modelled as a Heaviside step function. The time-independent Schrödinger equation for the wave function ψ ( x ) {displaystyle psi (x)} is where H is the Hamiltonian, ħ is the reduced Planck constant, m is the mass, E the energy of the particle. The step potential is simply the product of V0, the height of the barrier, and the Heaviside step function: The barrier is positioned at x = 0, though any position x0 may be chosen without changing the results, simply by shifting position of the step by −x0. The first term in the Hamiltonian, − ℏ 2 2 m d 2 d x 2 ψ {displaystyle -{frac {hbar ^{2}}{2m}}{frac {d^{2}}{dx^{2}}}psi } is the kinetic energy of the particle. The step divides space in two parts: x < 0 and x > 0. In any of these parts the potential is constant, meaning the particle is quasi-free, and the solution of the Schrödinger equation can be written as a superposition of left and right moving waves (see free particle) where subscripts 1 and 2 denote the regions x < 0 and x > 0 respectively, the subscripts (→) and (←) on the amplitudes A and B denote the direction of the particle's velocity vector: right and left respectively. The coefficients 1/√k1 and 1/√k2 are normalization constants. The wave vectors in the respective regions being both of which have the same form as the De Broglie relation (in one dimension)

[ "Electrode", "Electrochemistry", "Fractional Schrödinger equation", "Theoretical and experimental justification for the Schrödinger equation", "Cottrell equation" ]
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