Valence isomer

In organic chemistry, two molecules are valence isomers when they are constitutional isomers that can interconvert through pericyclic reactions.BenzeneDewar benzenePrismaneBenzvaleneBicyclopropenylCyclooctatetraene (COT)BarreleneCubaneCuneaneSemibullvalene1,5-dihydropentalene2a,2b,4a,4b-TetrahydrocyclopropapentaleneBicycloocta-2,4,7-triene. Tautomer with COT by thermal 6e process or photochemical 4e process Tricycloocta-3,8-diene. Isomerises to semibullvalene at room temperature, stable at −60 °C Tricycloocta-3,7-diene. The dimer of cyclobutadiene occurs as a cis isomer and a trans isomer. Both isomers convert to COT (symmetry forbidden hence stable) with a half-life of 20 minutes at 140 °C Tetracyclo octa-7-ene is only known as its 4-carbomethoxy derivative.Tetracyclo octa-7-ene has been prepared from benzvalene and isomerises to COT Pentacyclooctane (octabisvalene) is the third saturated valence isomer. The (Z)-3,7-phenylsulfonyl derivative is stable up to 200 °C.Tricycloocta-3,5-diene (octavalene) was reported synthesised from homobenzvalene and converts to COT at 50 °C NaphthaleneAzulene In organic chemistry, two molecules are valence isomers when they are constitutional isomers that can interconvert through pericyclic reactions. There are many valence isomers one can draw for the C6H6 formula benzene. Some were originally proposed for benzene itself before the actual structure of benzene was known. Others were later synthesized in lab. Some have been observed to isomerize to benzene, whereas others tend to undergo other reactions instead, or isomerize by ways other than pericyclic reactions. The valence isomers are not restricted to isomers of benzene. Valence isomers are also seen in the series (CH)8. Due to the larger number of units, the number of possible valence isomers is also greater and at least 21: