Highly cis-Selective Horner-Wadsworth-Emmons (HWE) Reaction of Methyl Bis(2,4-difluorophenyl)phosphonoacetate.

Keisuke Kokin,Jiro Motoyoshiya,Sadao Hayashi,Hiromu Aoyama

Highly cis-Selective Horner-Wadsworth-Emmons (HWE) Reaction of Methyl Bis(2,4-difluorophenyl)phosphonoacetate.

2010

Keisuke Kokin
Jiro Motoyoshiya
Sadao Hayashi
Hiromu Aoyama

Abstract Of the previously reported Horner-Wadsworth-Emmons (HWE) reaction, the olefination of methyl bis(2,4-difluorophenyl)phosphonoacetate (la) with various aldehydes gave unsaturated esters in the highest cis-selectivity.

Keywords:

Organic chemistry
Chemistry

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