Cp*Rh(III)-catalyzed C(sp3)H alkenylation and arylation of 8-methylquinolines with quinones and thiophenes

Abstract Rh(III)-catalyzed oxidative cross-coupling of C(sp 3 ) H bonds with C(sp 2 ) H bonds has been accomplished under mild conditions. This method furnishes a streamlined route for the C(sp 3 ) H alkenylation and arylation of 8-methylquinolines. This protocol enables 8-methylquinolines to couple with different quinone and thiophene derivatives.