Dreikomponentenreaktionen. XVII. Endständig reaktive Oligooxyethylenstrukturen aus Alkenen, Chlor und O‐Nucleophilen und deren Umsetzung zu Oxathiaalkanen

Three Component Reactions. XVII. Terminal Reactive Oligooxyethylene Structures from Alkenes, Chlorine and O-Nucleophiles and Their Transformation into Oxathiaalkanes The reaction of alkenes, chlorine and oxirane, dioxane, ethyleneglycole, oligoethylenglycoles, the monoethers of oligoethyleneglycoles, ethylene chlorohydrine or α-hydro-ω-chloro-oligooxyethylenes leads to compounds 6--9, which contain mono or oligoether functions and one or two reactive terminal chlorine atoms. Oxathiaalkanes (10 and 12) were obtained in the reaction of such compounds with sodium mercaptides.