Elevational and spatial variation in daytime ozone concentrations in the Virginia Blue Ridge Mountains: implications for forest exposure

Ozone (O3) concentrations before and during the early growing season were monitored continuously at two closely located areas in the Virginia Blue Ridge Mountains: a deciduous forest watershed (Shaver Hollow) and a predominantly open grassy meadow (Big Meadows). In addition, O3 concentrations and canopy development (percent leaf emergence) were measured simultaneously at three sites along the elevational gradient of the Shaver Hollow watershed. When the canopy at Shaver Hollow was leafless, patterns of O3 concentration were similar between the forest and meadow, increasing steadily toward early spring, with low variability of hourly daytime measurements. Greater differences in O3 concentration between forest and meadow and higher variability occurred during the period May-June, a time when the canopy changed from 15 to 100% leaf emergence. Several factors varying along the elevational gradient, related to both canopy structure and meteorological conditions, appeared to be important in affecting absolute O...