A scanning electrochemical microscopy characterization of the localized corrosion reactions occurring on nitinol in saline solution after anodic polarization

Abstract Scanning electrochemical microscopy (SECM) in a combined amperometric/potentiometric operation was used to characterize the electrochemical activity of nitinol, before and after anodic treatment, in 0.1 M NaCl solution. The SECM operation in the feedback mode showed that the nitinol surface was homogeneously passive after surface finishing and storage under ambient conditions, while heterogeneous surface characteristics occurred after application of anodic polarization, even for a limited time. That is, the development of anodic and cathodic sites has been detected due to the onset of localized corrosion processes on the metal surface. The evolution of hydrogen gas from localized sites was monitored using SECM in the substrate generation/tip collection mode (SG/TC), while SECM operated in potentiometric mode was used to map the pH distribution in the electrolyte volume adjacent to the nitinol surface. Local acidification was observed around anodic spots associated with the Ni2+ discharge, as well as alkalinization above the cathodic zones.