Highly Sterically Encumbered Gold Acyclic Diaminocarbene Complexes: Overriding Electronic Control in Regiodivergent Gold Catalysis

Aaron A. Ruch,Matthew C. Ellison,John K. Nguyen,Fanji Kong,Sachin Handa,Vladimir N. Nesterov,LeGrande M. Slaughter

Highly Sterically Encumbered Gold Acyclic Diaminocarbene Complexes: Overriding Electronic Control in Regiodivergent Gold Catalysis

2021

Aaron A. Ruch
Matthew C. Ellison
John K. Nguyen
Fanji Kong
Sachin Handa
Vladimir N. Nesterov
LeGrande M. Slaughter

Two series of sterically encumbered gold(I) acyclic diaminocarbene (ADC) complexes were prepared by reaction of mono- and dialkylamines with gold-bound 2-mesitylphenyl isocyanide (monomesityl serie...

Keywords:

Isocyanide
Combinatorial chemistry
Chemistry
Steric effects
Catalysis

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