Stereochemistry of Linoleic Acid Esters of HydroxyLinoleic Acids
2019
The
syntheses of linoleic acid esters of hydroxy linoleic acids (LAHLAs)
present in oat oil and human serum have been achieved, providing access
to material for testing and the determination of the stereochemistry
of the natural compounds. While 9- and 13-LAHLAs were found to be
a mixture of enantiomers 15-LAHLA is generated in a single optical
form in oat oil. The stereochemistry of 15-LAHLA in oat oil was found
to be opposite to that reported for digalactosyldiacylglycerol that
possesses an embedded 15-LAHLA.
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