Brønsted acid/visible-light-promoted Markovnikov hydroamination of vinylarenes with arylamines

Jiao Gui,Haisheng Xie,Fengjuan Chen,Zhipeng Liu,Xiaoqi Zhang,Fubin Jiang,Wei Zeng

Brønsted acid/visible-light-promoted Markovnikov hydroamination of vinylarenes with arylamines

2020

Jiao Gui
Haisheng Xie
Fengjuan Chen
Zhipeng Liu
Xiaoqi Zhang
Fubin Jiang
Wei Zeng

A Bronsted acid/visible-light-promoted Markovnikov hydroamination of vinylarenes with arylamines in the presence of TPT and CF3CO2H has been developed. This transformation provides a green approach to alpha-amino-substituted arylalkanes under metal-free conditions.

Keywords:

Brønsted–Lowry acid–base theory
Chemistry
Hydroamination
Photochemistry
Organic chemistry
Visible spectrum
Markovnikov's rule

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