Synthesis and structural features of new pentacoordinated monofluorosilanes containing C,O-chelate ligands based on 2-amino acid N -methylamides
2018
Pentacoordinated monofluorosilanes R1SO2NHCHR2C(O)N(Me)CH2SiMe2F containing moieties of N′-methyl-N-(organosulfonyl)-2-amino acid amides of glycine, alanine, and leucine as C,O-chelating ligands were synthesized via the reaction of corresponding disiloxanes with BF3•Et2O. The structures of obtained compounds were investigated by single-crystal X-ray diffraction analysis.
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