Non-catalyzed, atom-economic, high-yield synthesis of tertiary α-hydroxyphosphane selenides
2006
First examples of a facile hydroselenophosphorylation of aldehydes are reported. Nucleophilic addition of P,Se-ambident secondary phosphane selenides to a series of aldehydes proceeds under catalyst-free conditions at room temperature to give tertiary α-hydroxyphosphane selenides in high yield.
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