2D Position-Sensitive Hybrid-Perovskite Detectors.

Hybrid organic-inorganic perovskites (HOIPs) have emerged as a versatile class of semiconductors for numerous optoelectronic applications. Here, we demonstrate light-excitation-dependent two-dimensional (2D) position-sensitive detectors (PSDs) using a mixed-phase perovskite, FA0.83Cs0.17Pb(I0.9Br0.1)3, as the active semiconductor, incorporated within a five-terminal device geometry. The light-induced lateral photovoltage, which is initiated by selective charge transfer across the metal-perovskite barrier interface, is utilized to achieve the excitation-position-dependent electric response. The 2D PSD devices exhibit a spatially dependent linear variation of the photosignal with sensitivity >50 μV mm-1 and a low position detection error (1-2%), making them suitable for applications such as quadrant detectors. Further, it is observed that the device architecture plays a key role in controlling the dynamics and linearity of the HOIP PSDs. The large active area devices (up to ∼2 cm × 2 cm) exhibit a distinct spatial variation of the photosignal. We utilize the functionality of the PSD device for light-tracking applications by implementing a continuous detection scheme.