Kinetics and Mechanism of the Autocatalytic Oxidation of Mn(II) by Bromine
2001
The oxidation of Mn(II) by bromine is an autocatalytic reaction, which seems to be important for a detailed elucidation of chemical oscillators, based on manganese chemistry. With regard to the mechanism proposed previously, an alternative reaction mechanism is proposed, based on a micro-heterogeneous oxidation of Mn(II) ion, adsorbed on a surface of the MnO2 colloid.
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