Design, synthesis, photophysical properties and intrinsic mechanism of two difluoroboron β-diketonate complexes with TPE and N-alkyl pyrrole units
2019
Abstract It is a hot topic to furnish aggregation-caused quenching luminogens with aggregation-induced emission (AIE) active units and explore their optical properties and inherent mechanism. In this paper, two newly designed and synthesized difluoroboron β-diketonate complexes ( TPE-BF 2 -2AP and TPE-BF 2 -2MP ) with tetra (phenyl) ethylene (TPE) and N -alkyl pyrrole unit exhibit solvatochromism, AIE and mechanochromic properties. Although the alkyl substituents with slight difference, TPE-BF 2 -2AP relative to TPE-BF 2 -2MP show distinct increased stokes shift and red shifted fluorescence emission in organic solvents. More interestingly, single crystal analysis reveals that TPE-BF 2 -2MP forms head-to-head anti-parallel stacking, while TPE-BF 2 -2AP adopts a scarce head-to-head cross non-parallel stacking, leading to enhanced quantum efficiency from 0.24 to 0.34 before/after grinding, and blue shifted fluorescence emission compared with TPE-BF 2 -2MP in aggregated states and crystalline states. In addition, the two luminogens exhibit multi-state emission properties by grinding, solvent fumigation and heating due to incomplete transformation between amorphous and crystalline state.
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