A Dual Supramolecular Crosslinked Polyurethane with Superior Mechanical Properties and Autonomous Self-Healing Ability

To prepare a robust material with high self-healing capability under ambient condition is still a great challenge. Herein, a novel self-healing polyurethane is developed via a dual-dynamic network design, in which multiple H-bonding and metal-coordinated bonds (zinc-imidazole interaction) were incorporated into a polyurethane matrix. Benefiting from the dual-dynamic network, the synthesized metallopolymers exhibit excellent mechanical properties, such as high tensile strength (from 6.68 MPa to 14.38 MPa), excellent stretchability (about 2000%) and superior toughness (from 55.61 MJ m-3 to 96.21 MJ m-3). Moreover, these metallopolymers show good self-healing capability. After healing under ambient condition for 48 hours, the tensile strength and strain at break of PU-IZ/Zn-0.50 can reach up to 7.13 MPa and 1800%, respectively. The dual-dynamic crosslinked metallopolymers might provide a novel approach to design tough and self-healable materials for various industrial applications.