Synthesis and Steady-State Spectroscopic Study of 5-Aryl-2,2′-bipyridyls. New Fluorescent Compounds in Solid State
2006
The absorption and fluorescent properties of newly synthesized 5-aryl-2,2'-bipyridyls were examined both in solution and in the solid state. The 6-methoxy derivatives 5a-5c have weak fluorescence, whereas 6-amino derivatives 7a-7f showed strong fluorescence. Their spectroscopic properties were computationally analyzed using semi-empirical molecular orbital calculations. The geometries of the ground (S 0 ) and the first singlet excitation states (S 1 ) were optimized and employed to estimate the vertical transition energies. The drastic differences in fluorescent intensities between 5a-5c and 7a-7f can be qualitatively explained by the relative energy levels S 1 and the neighboring triplet level: the energy gaps supposedly regulate the non-radiative intersystem crossing (ISC) probabilities. On the relaxed S 1 geometry. 5a-5c have quite small S 1 -triplet energy gaps, whereas 7a-7f have no such quasi-degeneracies, leading to their quantitatively different quantum yields.
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