The visual spectrum of Jupiter's Great Red Spot accurately modeled with aerosols produced by photolyzed ammonia reacting with acetylene

Abstract We report results incorporating the optical properties of the red-tinted photochemically-generated aerosols of Carlson et al. (2016, Icarus 274, 106–115) in spectral models of Jupiter's Great Red Spot (GRS). This material - created in laboratory GRS simulations from acetylene reacting with photolytic products of ammonia produced by ~0.2-μm radiation, similar to solar radiation on Jupiter within and above the upper troposphere, provides an excellent match to 0.35–1.05-μm spectra of the core of the Great Red Spot obtained by the Visual Infrared Mapping Spectrometer (VIMS) during the 2000–2001 Cassini-Huygens flyby. Radiative transfer models of GRS spectra acquired near the central-meridian (CM) and limb by the visual channel of the Cassini/VIMS near closest approach on December 31, 2000 and January 2, 2001, respectively, show remarkable agreement for model morphologies where the following conditions all exist: (1) most of the optical depth of the Carlson et al. (2016) chromophore resides near the top or above the main cloud layer, rather than being uniformly distributed within it, (2) the chromophore consists of relatively small particles in the 0.1–0.2 μm range, and (3) the 1-μm optical depth of the chromophore layer is small, of the order of 0.1–0.2. For such models, the chromophore layer mass abundance is 32–40 μgm cm −2 . Consideration of the availability of the acetylene and ammonia parent gas material near the observed chromophore layers gives powerful support for the chromophore residing at the top of the main cloud in the upper troposphere rather than residing as a detached layer in the stratosphere. Under steady-state formation/loss conditions, consideration of plausible eddy diffusion coefficients pertaining to the relatively quiescent Jovian upper atmosphere yield untenable vertical transport times of more than several centuries required to supply the acetylene needed to form the chromophore layer, with stratospheric chromophore models requiring more than half a millennium. Consideration of the convective nature of the GRS and possible presence of acetylene-generating thunderstorms yields upper-troposphere chromophore layer formation times ranging from 11 years to 1.5 months for (1) plausible eddy diffusion coefficients ranging from 10 4 to 10 6  cm 2  s −1 and (2) efficient conversion of C 2 H 2 and NH 3 into the Carlson et al. (2016) chromophore. Thus, the enhanced red coloring of the GRS may be due to the combined effects of (1) the relatively high, 0.2-bar cloudtop where ammonia ice and gas are delivered to prime photo-dissociation altitudes, by (2) powerful convection, which also delivers acetylene from depth created by (3) lightning, which is itself a by-product and indicator of powerful convection, and aided by (4) the vortex nature of the GRS, which helps to confine and concentrate the chromophore as it forms over time within the GRS anticyclone.