Stereoselective synthesis of spirocyclic nitronates by SnCl4-promoted reaction of nitroalkenes with C-2 substituted 4-methylidene-1,3-dioxolane
2015
SnCl 4 -promoted [4 + 2] cycloaddition of β-nitrostyrenes to 4-methylidene-1,3-dioxolane provides stereoselective synthesis of spirocyclic nitronates. 2-Nitrovinyl benzoate under the same conditions produces δ-substituted nitrodiene as a single E,E -isomer.
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