Total Synthesis of (-)-Sigillin A: A Polychlorinated and Polyoxygenated Natural Product.
2020
The total synthesis of (−)-sigillin A, a highly chlorinated and oxygenated octahydroisocoumarin, is described herein. A hexahydroisocoumarin skeleton was constructed from (R)-4-(trichloromethyl)oxe...
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