Synthesis and characterization of amylose grafted poly(acrylic acid) and its application in ammonia adsorption

Abstract Amylose grafted poly(acrylic acid) (Am- g -PAA) was synthesized by graft copolymerization of amylose with acrylic acid. The structure of Am- g -PAA was confirmed by 1 H NMR and FT-IR spectra. The morphology, crystallinity and thermal properties of amylose and Am- g -PAA were investigated by SEM, XRD and TGA, respectively. The highest degree of substitution (DS) of carboxyl group was 1.96 which was obtained after reacted for 1 h at 60 °C. Acrylic acid to anhydroglucose mole ratio for DS was 19.81. It was found that a large number of carboxyl groups were grafted on the backbone of amylose. It was also found that ammonia adsorption capacity of amylose increased by grafting poly(acrylic acid) on the backbone of amylose.