Characterization of Navajo Sandstone concretions: Mars comparison and criteria for distinguishing diagenetic origins

Abstract The eolian Jurassic Navajo Sandstone spheroidal hydrous ferric oxide (HFO) concretions are divided into two size classes: macro-concretions of > 5 mm diameter and micro-concretions of Chemical and mineralogical gradients (μm- to mm-scale) are identified with QEMSCAN (Quantitative Elemental Mineralogy using a SCANning electron microscope) and visible to near infrared (VNIR) reflectance spectroscopy. Three HFO phases are identified using VNIR reflectance spectroscopy. i. An amorphous HFO phase is typically located in the rinds. ii. Goethite is present along interior edges of rinds and throughout the interiors of layered and solid concretions. iii. Hematite is present in the centers of rind concretions. A synthesis of petrographic, mineralogical and chemical analyses suggests that concretions grow pervasively (as opposed to radially expanding). Our model proposes that concretions precipitate initially as an amorphous HFO that sets the radius and retains some original porosity. Subsequent precipitation fills remaining pore space with younger mineral phases. Inward digitate cement crystal growth corroborates concretion growth from a set radius toward the centers. Internal structure is modified during late stage precipitation that diffuses reactants through semi-permeable rinds and overprints the interiors with younger cements. Physical characterization of textures and minerals provides diagnostic criteria for understanding how similar concretions (“blueberries”) form in Meridiani Planum, Mars. The analogous Navajo Sandstone concretions show similar characteristics of in situ self-organized spacing, spheroidal geometries, internal structures, conjoined forms, and precursor HFO phases that dehydrate to goethite or hematite. These characteristics indicate a common origin via groundwater diagenesis.