High temperature Fe(III) spin crossover behaviours in three uprecedented FeIII‒MII‒FeIII (M = Fe, Cd) linear trinuclear complexes

Zhi-Jian Ouyang,Xiao-Ying Mo,Meng Yang,Li Zhong,Wen-Bin Chen,Song Gao,Wen Dong

High temperature Fe(III) spin crossover behaviours in three uprecedented FeIII‒MII‒FeIII (M = Fe, Cd) linear trinuclear complexes

2020

Zhi-Jian Ouyang
Xiao-Ying Mo
Meng Yang
Li Zhong
Wen-Bin Chen
Song Gao
Wen Dong

An azo-based ligand of azotetrazolyl-2,7-dihydroxynaphthalene (H3ATD) was used to synthesize three unprecedented FeIII–MII–FeIII (M = Fe, Cd) linear trinuclear complexes with different high temperature spin crossover (SCO) behaviours for the terminal FeIII ions.

Keywords:

Chemistry
Crystallography
Spin crossover
Ion
Ligand

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