Stereocontrolled Synthesis of Bicyclic Sulfamides via Pd‐Catalyzed Alkene Carboamination Reactions. Control of 1,3‐Asymmetric Induction by Manipulating Mechanistic Pathways.

Optimized conditions concerning the substrates, the catalyst and the reaction medium favor the desired anti-aminopalladation mechanism to produce the ring systems with a reversed relative stereochemistry at C-3/C-4.