Synthesis of amino-functionalized biochar/spinel ferrite magnetic composites for low-cost and efficient elimination of Ni(II) from wastewater.

Abstract Novel amino-modified rice bran biochar/MgFeAlO4 (RB@MgFeAlO4-NH2) magnetic composites were synthesized via a simple one-step solvothermal approach and applied for removing toxic Ni(II) from wastewater. The elimination process and sorption performance of Ni(II) on RB@MgFeAlO4-NH2 were analyzed by combining batch experiments and spectral techniques. The sorption isotherms and kinetic data indicated that Ni(II) sorption on RB@MgFeAlO4-NH2 was monolayer and rapid. The experimental results confirmed that the obtained RB@MgFeAlO4-NH2 magnetic composite had high sorption capacity for Ni(II). The maximum sorption capacity of Ni(II) on RB@MgFeAlO4-NH2 was 201.62 mg g−1. The researches based on the sorption mechanism showed that the ion exchange mechanism accounted for 76.51% of Ni(II) sorption. In addition, the amino, carboxyl and hydroxyl functional groups were also involved in the complexation with Ni(II). In view of its multiple advantages of environmental friendliness, low cost, easy magnetic separation and high sorption capacity, RB@MgFeAlO4-NH2 will be an excellent adsorbent for low-cost and efficient elimination of Ni(II) from aqueous solutions.