Degenerate thermal isomerizations of bicyclo[3.1.1]hept‐2‐ene: strategy and analysis
2014
Bicyclo[3.1.1]hept-2-ene was first prepared and well identified in 1972. In 1974, the degenerate thermal isomerization involving 1-d- and 3-d-bicyclo[3.1.1]hept-2-ene was approached successfully, as one of the two deuterium-labeled structures was selected, heated, and equilibrated. There has been no further study of this degenerate isomerization. Here, a detailed outline of reaction trajectories for d2-labeled bicyclo[3.1.1]hept-2-enes is given that will establish the four independent kinetic parameters needed for 20 linking paths between six d2-species. The use of racemates, eliminating chiral separations and dissections, provides degenerate isomerization paths providing this method with general utility. Copyright © 2014 John Wiley & Sons, Ltd.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
25
References
0
Citations
NaN
KQI