Synthesis and characterization of ITr-protected group 11 metal trimethylsilylchalcogenolates

This work describes the synthesis of group 11 metal trimethylsilylchalcogenolate complexes [(ITr)M-ESiMe3] stabilized by the large NHC ligand bis-1,3-tritylimidazole-2-ylidene (ITr). The thiolates ...