Diazido-bis[2,4-diamino-6-(2-pyrid-yl)-1,3,5-triazine-κN,N]zinc(II).
2009
In the title mononuclear complex, [Zn(N3)2(C8H8N6)2], the ZnII atom, lying on a twofold rotation axis, is six-coordinated in a distorted octahedral environment by four N atoms from two 2,4-diamino-6-(2-pyridyl)-1,3,5-triazine ligands and two N atoms from two end-on-coordinated azide ions. N—H⋯N hydrogen bonds between the ligand and azide ion link the complex molecules into a three-dimensional network.
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KQI