Atomic layer deposition of Ti-HfO2 dielectrics
2013
Titanium-doped hafnium oxide films, TixHf1−xO2−δ, have been deposited with a Ti content of x = 0.1 and x = 0.5, by atomic layer deposition. The TixHf1−xO2−δ growth rate is lower compared with the growth rates of the individual binary oxides; however, the composition of the films is unaffected by the reduced growth rate. An 850 °C spike anneal and a 500 °C 30 min furnace anneal were performed, and the resulting film composition and structure was determined using medium energy ion scattering, x-ray diffraction, and transmission electron microscopy. The Ti0.1Hf0.9O2−δ films readily crystallize into a monoclinic phase during both types of annealing. By contrast, the Ti0.5Hf0.5O2−δ films remain amorphous during both annealing processes. Electrical characterization of the as-deposited Ti0.1Hf0.9O2−δ films yielded a dielectric constant of 20, which is slightly higher than undoped HfO2 films. The as-deposited Ti0.5Hf0.5O2−δ films showed a significant increase in dielectric constant up to 35. After a 500 °C 30 ...
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
39
References
5
Citations
NaN
KQI