Gravity Analog Model of Non-equilibrium Thermodynamics
2018
Non-equilibrium thermodynamics of Onsager and Machlup and of Hashitsume is reformulated as a gravity analog model, in which thermodynamic variables, kinetic coefficients and generalized forces form, respectively, coordinates, metric tensor and vector fields in a space of thermodynamic variables. The relevant symmetry of the model is the general coordinate transformation. Then, the entropy production is classified into three categories, when a closed path is depicted as a thermodynamic cycle. One category is time reversal odd, and is attributed to the number of magnetic fluxes passing through the closed path, having monopole as a source. There are two time reversal even categories, one of which is attributed to the space curvature around the path, having gravitational instanton as a source, which dominates for a rapid operation of the cycle. The last category is the usual one, which remains even for the quasi-equilibrium operation. It is possible to extend the model to include non-linear responses. In introducing new terms, important is the dimensional counting, using two parameters, the temperature and the relaxation time. Fluctuation-dissipation theorem is examined {\it \`a la} Onsager, and a derivation of the gravity analog thermodynamic model from quantum mechanics is sketched, based on an analogy to the resonance problem.
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