Assignment of the surface core-level shifts to the surface layers of Be(10(1)over-bar0)

Photoemission studies and layer resolved Korringa-Kohn-Rostoker (KKR) multiple scattering calculations are used to find the assignment of the surface core-level shifts to the top layers of the Be(10 (1) over bar0) surface. Striking similarities between experimental and calculated data make it possible to assign the largest shift to layer two, the second largest shift to layers three and four, and the smallest shift to layer one.