Excitation-Wavelength-Dependent and Auxiliary-Ligand-Tuned Intersystem-Crossing Efficiency in Cyclometalated Platinum(II) Complexes: Spectroscopic and Theoretical Studies

Kai Li,Glenna So Ming Tong,Jia Yuan,Chensheng Ma,Lili Du,Chen Yang,Wai Ming Kwok,David Lee Phillips,Chi-Ming Che

Excitation-Wavelength-Dependent and Auxiliary-Ligand-Tuned Intersystem-Crossing Efficiency in Cyclometalated Platinum(II) Complexes: Spectroscopic and Theoretical Studies

2020

Kai Li
Glenna So Ming Tong
Jia Yuan
Chensheng Ma
Lili Du
Chen Yang
Wai Ming Kwok
David Lee Phillips
Chi-Ming Che

Understanding the factors affecting the intersystem-crossing (ISC) rate constant (kISC) of transition-metal complexes is crucial to material design with tailored photophysical properties. Most of t...

Keywords:

Reaction rate constant
Photochemistry
Chemistry
Ligand
Platinum
Intersystem crossing
excitation wavelength

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