Interfacial reaction behavior and bonding mechanism between liquid Sn and ZrO2 ceramic exposed in ultrasonic waves

Abstract Ultrasound-assisted dipping of ZrO 2 ceramics into molten Sn solder was performed to realize the low-temperature joining of ZrO 2 ceramics in this study. Scanning electron microscopy with energy dispersive spectrometer, X-ray diffraction and X-ray photoelectron spectroscopy were employed to study the effects of ultrasonic vibration on the microstructure of Sn/ZrO 2 interface, and to elucidate the joining mechanism between Sn coating layer and ZrO 2 ceramic. Results showed that, after ultrasonically dipping in molten Sn for 1200 s, a pure Sn solder layer with a thickness of approximately 8–9 µm was coated on the ZrO 2 surface. The Sn coating layer exhibited excellent metallurgic bonding with ZrO 2 ceramic. A nano-sized ZrSnO 4 ternary phase, which was beneficial to the smooth transition of the lattice from Sn solder to ZrO 2 ceramic, was formed at the Sn/ZrO 2 interface. The formation of ZrSnO 4 interlayer was ascribed to the acoustic cavitation induced high-temperature reaction of Sn, O and ZrO 2 at the molten Sn/ZrO 2 ceramic interface. The tested average shear strength of ZrO 2 /Sn/ZrO 2 joints was approximately 32 MPa, and the shearing failure mainly took place within the Sn solder layer.