[3+2]-Annulation of platinum-bound azomethine ylides with distal CC bonds of N-allenamides
2017
A Pt-catalyzed, highly regioselective reaction between N-allenamides and imino-alkynes leading to pyrrolo[1,2-a]indoles is described. This represents the first example of [3+2]-annulation of Pt-bound azomethine ylides with the distal CC bond of N-allenamides. The mechanism of the reaction was established by computational studies.
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