Influence of thermal processing conditions in 3D printing on the crystallinity and mechanical properties of PEEK material

Abstract Poly-ether-ether-ketone (PEEK) is a high-performance, temperature-resistant semicrystalline polymer which is frequently used as a replacement for metals in a wide variety of high-performance end-use application. Thermal processing conditions during manufacturing process for PEEK can implement a significant impact on its crystallinity and mechanical properties directly and indirectly. In this paper, we have used a temperature-control 3D printing system to prepare all the PEEK samples for calculating crystallinity and performing tension tests, in order to investigate the relationship between various thermal processing conditions (the ambient temperature, the nozzle temperature and heat treatment methods) in FDM process and crystallinity and mechanical properties (tensile strength, elastic modulus and breaking elongation) of pure PEEK material. All experiment results show temperature-control 3D printing method has tremendous potential to design, control and realize different degrees of crystallinity and mechanical properties for different PEEK parts, even in different regions of the same PEEK part.