Highly Enantioselective Hydrogenation of N‐Aryl Imines Derived from Acetophenones by Using Ru‐Pybox Complexes under Hydrogenation or Transfer Hydrogenation Conditions in Isopropanol.

Estefanía Menéndez‐Pedregal,Mónica Vaquero,Elena Lastra,Pilar Gamasa,Antonio Pizzano

Highly Enantioselective Hydrogenation of N‐Aryl Imines Derived from Acetophenones by Using Ru‐Pybox Complexes under Hydrogenation or Transfer Hydrogenation Conditions in Isopropanol.

2015

Estefanía Menéndez‐Pedregal
Mónica Vaquero
Elena Lastra
Pilar Gamasa
Antonio Pizzano

The asymmetric reduction of N-aryl imines derived from acetophenones by using Ru complexes bearing both a pybox and a monodentate phosphite ligand is described.

Keywords:

Enantioselective synthesis
Medicinal chemistry
Transfer hydrogenation
Denticity
Aryl
Chemistry
Ligand
Organic chemistry

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