Ring Expansions Within the Gold-Catalyzed Cycloisomerization of O-Tethered 1,6-Enynes. Application to the Synthesis of Natural-Product-like Macrocycles

Antoine Simonneau,Youssef Harrak,Louis Jeanne-Julien,Gilles Lemière,Virginie Mouriès-Mansuy,Jean-Philippe Goddard,M. Malacria,Louis Fensterbank

Ring Expansions Within the Gold-Catalyzed Cycloisomerization of O-Tethered 1,6-Enynes. Application to the Synthesis of Natural-Product-like Macrocycles

2013

Antoine Simonneau
Youssef Harrak
Louis Jeanne-Julien
Gilles Lemière
Virginie Mouriès-Mansuy
Jean-Philippe Goddard
M. Malacria
Louis Fensterbank

The gold-catalyzed cycloisomerization of O-tethered 1,6-enynes proceeds via a small-sized ring expansion leading to the tricyclic compounds that contain a substituted dihydropyran moiety.

Keywords:

Natural product
Tricyclic
Moiety
Cycloisomerization
Catalysis
Organic chemistry
Dihydropyran
Chemistry
Photochemistry

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